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Place the following in order of increasing F-A-F bond angle,where A represents the central atom in each molecule. PF3 \quad OF2 \quad PF4+


A) PF3 < OF2 < PF4+
B) OF2 < PF3 < PF4+
C) OF2 < PF4+ < PF3
D) PF4+ < OF2 < PF3
E) PF4+ < PF3 < OF2

F) B) and C)
G) A) and E)

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Place the following in order of increasing dipole moment. I.BCl3 \quad II.BIF2 \quad III.BClF2


A) I < II = III
B) II < III < I
C) I < II < III
D) II < I < III
E) I < III < II

F) B) and D)
G) A) and B)

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In molecular orbital theory the acronym LUMO stands for


A) lowest unhybridized molecular orientation.
B) lowest unoccupied molecular orbital.
C) lowest unhybridized molecular orbital.
D) linear-uninteresting molecular orientation.
E) It has no meaning.

F) C) and D)
G) B) and D)

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Identify the number of electron groups around a molecule with sp2 hybridization.


A) 1
B) 2
C) 3
D) 4
E) 5

F) D) and E)
G) B) and D)

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Place the following in order of decreasing dipole moment. I.cis-CHCl=CHCl \quad II.trans-CHCl=CHCI \quad III.cis-CHF=CHF


A) III > I > II
B) II > I > III
C) I > III > II
D) II > III > I
E) I = III > II

F) B) and D)
G) A) and B)

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Determine the molecular geometry about each interior atom in the following structure.Sketch the three-dimensional structure and label the interior atoms with the corresponding molecular geometry. CH2CHCCCH3

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The sketch should show all of the approp...

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Using the VSEPR model,the molecular geometry of the central atom in XeCl4 is ________.


A) tetrahedral
B) seasaw
C) trigonal bipyramidal
D) square pyramidal
E) square planar

F) D) and E)
G) B) and E)

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Explain why oil and water do not mix.

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Water molecules are ...

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What are the F-Po-F bond angles in PoF6 ?


A) 60°
B) 90°
C) 109.5°
D) 120°

E) C) and D)
F) A) and D)

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Draw the Lewis structure for CCl4.What is the hybridization on the C atom?


A) sp
B) sp3d2
C) sp3d
D) sp3
E) sp2

F) A) and B)
G) B) and D)

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A molecule or ion with eight electrons in bonding orbitals and two electrons in an antibonding orbital has a bond order of:


A) 1
B) 1.5
C) 2
D) 2.5
E) 3

F) A) and B)
G) A) and C)

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Determine the electron geometry (eg) and molecular geometry (mg) of the underlined atom CH3OCH3.


A) eg = tetrahedral,mg = tetrahedral
B) eg = linear,mg = linear
C) eg = tetrahedral,mg = bent
D) eg = trigonal bipyramidal,mg = tetrahedral
E) eg = octahedral,mg = square planar

F) A) and B)
G) All of the above

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Using the VSEPR model,the molecular geometry of the central atom in SeO2 is ________.


A) linear
B) tetrahedral
C) bent
D) trigonal planar
E) trigonal pyramidal

F) B) and C)
G) B) and E)

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Draw the Lewis structure for COCl2.What is the hybridization on the C atom?


A) sp
B) sp3d2
C) sp3d
D) sp3
E) sp2

F) B) and D)
G) A) and E)

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Determine the electron geometry (eg) and molecular geometry (mg) of the underlined carbon in CH3CN.


A) eg = tetrahedral,mg = tetrahedral
B) eg = linear,mg = trigonal planar
C) eg = trigonal planar,mg = bent
D) eg = linear,mg = linear
E) eg = trigonal planar,mg = trigonal planar

F) All of the above
G) A) and E)

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Determine the electron geometry (eg) and molecular geometry (mg) of SiF4.


A) eg = tetrahedral,mg = trigonal pyramidal
B) eg = octahedral,mg = square planar
C) eg = trigonal bipyramidal,mg = trigonal pyramidal
D) eg = tetrahedral,mg = bent
E) eg = tetrahedral,mg = tetrahedral

F) A) and E)
G) All of the above

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What is the O-B-O bond angle in BO33-?


A) less than 109.5°
B) 109.5°
C) 120°
D) greater than 120°

E) A) and B)
F) A) and C)

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Give the approximate bond angle for a molecule with octahedral electron geometry and square planar molecular geometry.


A) 90°
B) 180°
C) >120°
D) <90°
E) <120°

F) C) and D)
G) A) and D)

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Determine the electron geometry (eg) and molecular geometry (mg) of the underlined atom CH3OCH3.


A) eg = tetrahedral,mg = tetrahedral
B) eg = linear,mg = linear
C) eg = tetrahedral,mg = bent
D) eg = trigonal bipyramidal,mg = tetrahedral
E) eg = octahedral,mg = square planar

F) A) and E)
G) D) and E)

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Determine the molecular geometry for the molecule SBr2.


A) Trigonal pyramidal
B) Trigonal planar
C) Tetrahedral
D) T-shaped
E) Bent

F) A) and E)
G) A) and D)

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